Experimental results have shown that for most practical purposes color
matches obey the rules of linearity and additivity. This principle, as
applied to color, is known as Grassmann's law. What this means, as a
practical matter, is that if two color stimuli
The consequence of Grassmann's law is that if the tristimulus values of
every monochromatic stimulus of unit radiance are known, the tristimulus
values of any other stimulus can be calculated by integration. Thus, if
the tristimulus values of all monochromatic stimuli are denoted as
per unit radiance, then the tristimulus values of a stimulus having a
spectral radiant distribution of
are
Experimental measurements of color matching have been carried out using
a significnt sample of people with normal color vision. A set of three
functions,
,
derived from these experiments have been used by the Commission
International de L'Éclairage (CIE) in 1931 as the basis of an
international standard. The three functions, known as color-matching
functions, are shown below.
At the same time these color-matching functions were adopted as a
standard, the CIE adopted another set of cleverly designed primary
stimuli that have special properties; they are designated as X, Y, and
Z, with corresponding tristimulus values X, Y, and
Z and color-matching functions
Although X, Y and Z are linearly related to R, G and B, they are
imaginary (non physical) primaries chosen so all luminance information
in any mixture of the three is contributed by Y. Another condition of
their choice makes the three color-matching functions have non-negative
values at all wavelengths. The color-matching functions shown below are
normalized to have equal valued integrals over the visible spectrum.
Figure: CIE 1931 color-matching functions
is replaced by either
or
,
where
is the spectral reflectance factor,
is the spectral transmittance factor and
is the spectral distribution of the illuminant. Thus,
is a perfect white-reflecting diffuser and
is a clear transmitting filter. The perceived color of any transmitting
or reflecting object is a funciton of the illuminant,
.
In 1964, the
CIE defined the spectral distribution functions of standard illuminants
and their correlated color temperatures (expressed in degrees Kelvin).
These illuminants, though mathematically defined as standards, are not
precisely realizable as physical sources. The illuminant chosen for our
viewing conditions is Illuminant
,
having a correlated color temperature of 5000° Kelvin. Illuminant
,
is approximately equivalent to natural noon-day sunlight on a bright but
slightly overcast day. The light source chosen for illuminating both
reflective and transmissive objects to be scanned in one configuration
of our digital imaging system is a tungsten-halogen bulb having a
correlated color temperature of 3250° Kelvin. The spectral
distributions of the chosen viewing illuminant and illuminating source
are shown here.
The above is based on the IBM Research Report RC19240 "Color Calibration for the TDI Pro Scanner" by Gordon W. Braudaway and Hon-Sum P. Wong.